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                                                                                                                                        Ukr  Eng             Íàçàä

 

Application of gas hydrate technologies for coal mine methane transportation

 

K.S. Sai1*

1Dnipro University of Technology, Dnipro, Ukraine

*Corresponding author: e-mail: kateryna.sai@gmail.com

 

Physical and technical problems of mining production, 2020, (22), 170-184.

 

https://doi.org/10.37101/ftpgp22.01.012

full text (pdf)

 

ABSTRACT

 

Purpose. Improving the efficiency of application of gas hydrate technologies for converting coal mine methane into a solid crystalline state with its subsequent transportation to consumers by intensifying the hydrate formation process.

Methods. Experimental studies were carried out in the laboratory of innovative technologies of the Dnipro University of Technology (Dnipro, Ukraine). The thermobaric parameters of the hydrate formation process varied to produce of gas hydrate samples from mine methane by artificial means. Physical modeling and field experiments were carried out in an ILKA KTK-3000 climate chamber, as well as on an NPO-5 unit, which made it possible to simulate specified thermobaric parameters (temperature, pressure). The least squares method was used to determine the linear regression parameters.

Findings. Gas hydrates and their thermobaric conditions were experimentally obtained under three variants: free mixing of gas and water in a reactor, forced mixing of a water-gas mixture and mixing of a water-gas mixture in a magnetic field. The functional relationship between the initial parameters of the hydrate formation process is determined for the three options considered. The adequacy of the constructed models was verified by calculating the determination coefficient for each model using the square of the linear correlation coefficient. It is reasonable to transportation of gas in a solid gas hydrate state due to the effect of self-preservation, which is safer and economically feasible.

Originality. By mathematical modeling found that the determination indices for all the considered variants of the hydrate formation process are larger than the determination coefficients, which confirms the fact that the parabolic model is more adequate.

Practical implications. The optimal method for intensification of the hydrate formation process for substantiating artificially created gas hydrates from coal mine methane as an alternative energy source is justified.

Keywords: gas hydrate, methane, crystallization centers, intensification, effect of self-preservation, transportation

 

REFERENCES

 

1. Khorolskyi, A., Hrinov, V., Mamaikin, O., & Demchenko, Y. (2019). Models and methods to make decisions while mining production scheduling. Mining of Mineral Deposits, 13(4), 53–62. https://doi.org/10.33271/mining13.04.053

2. Petlovanyi, M., Lozynskyi, V., Saik, P., & Sai, K. (2019). Predicting the producing well stability in the place of its curving at the underground coal seams gasification. E3S Web of Conferences, (123), 01019. https://doi.org/10.1051/e3sconf/201912301019

3. Khorolskyi, A., Hrinov, V., & Kaliushenko, O. (2019). Network models for searching for optimal economic and environmental strategies for field development. Procedia Environmental Science, Engineering and Management, 6(3), 463–471.

4. 95/05871 Coal-bed methane in Ukraine: Facta and prospects. (1995). Fuel and Energy Abstracts, 36(6), 418. https://doi.org/10.1016/0140-6701(95)97514-k

5. Alsaab, D., Elie, M., Izart, A., Sachsenhofer, R.F., Privalov, V.A., Suarez-Ruiz, I., & Panova, E.A. (2009). Distribution of thermogenic methane in Carboniferous coal seams of the Donets Basin (Ukraine): “Applications to exploitation of methane and forecast of mining hazards.” International Journal of Coal Geology, 78(1), 27–37. https://doi.org/10.1016/j.coal.2008.09.004

6. Boger, C., Marshall, J.S., & Pilcher, R.C. (2014). Worldwide coal mine methane and coalbed methane activities. Coal Bed Methane, 351–407. https://doi.org/10.1016/b978-0-12-800880-5.00018-8

7. Ganushevych, K., Sai, K., & Korotkova, A. (2014). Creation of gas hydrates from mine methane. Progressive Technologies of Coal, Coalbed Methane, and Ores Mining, 505–509. https://doi.org/10.1201/b17547-85

8. Cai, J., Xu, C., Xia, Z., Chen, Z., & Li, X. (2017). Hydrate-based methane recovery from coal mine methane gas in scale-up equipment with bubbling. Energy Procedia, (105), 4983–4989. https://doi:10.1016/j.egypro.2017.03.996

9. Diedich, I., & Nazimko, V. (2014). Assessment of goaf degassing wells shear due to their longwall undermining. Progressive Technologies of Coal, Coalbed Methane, and Ores Mining, 137–140. https://doi:10.1201/b17547-25

10. Carroll, J. (2014). Natural gas hydrates: a guide for engineers. Oxford, United Kingdom: Elsevier, 340 p.

11. Makogon, Y.F. (1997). Hydrates of hydrocarbons. Tulsa, Oklahoma, United States: Pennwell Books, 482 p.

12. Sai, K., Malanchuk, Z., Petlovanyi, M., Saik, P., & Lozynskyi, V. (2019). Research of thermodynamic conditions for gas hydrates formation from methane in the coal mines. Solid State Phenomena, (291), 155–172. https://doi.org/10.4028/www.scientific.net/ssp.291.155

13. Hrinov, V.H., Khorolskyi, A.O., & Kaliushchenko, O.P. (2019). Elaboration of environmental scenarios for the effective development of valuable mineral deposits. Mineral Resources of Ukraine, (2), 46–50. https://doi.org/10.31996/mru.2019.2.46-50

14. Petlovanyi, M., Sai, K., & Prokopenko, K. (2019). Prospects of utilization mining methane on the basis of gas hydrate technologies. Topical Issues of the Development of Modern Science: Abstracts of III International Scientific and Practical Conference. Sofia, Bulgaria: Publishing House “ACCENT”, 396–402.

15. Bondarenko, V., Svietkina, O., & Sai, K. (2018). Effect of mechanoactivated chemical additives on the process of gas hydrate formation. Eastern-European Journal of Enterprise Technologies, 1(6(91)), 17–26. https://doi.org/10.15587/1729-4061.2018.123885

16. Ovchynnikov, M., Ganushevych, K., & Sai, K. (2013). Methodology of gas hydrates formation from gaseous mixtures of various compositions. Annual Scientific-Technical Collection – Mining of Mineral Deposits 2013, 203–206. https://doi.org/10.1201/b16354-36

17. Kobayashi, I., Ito, Y., & Mori, Y. H. (2001). Microscopic observations of clathrate-hydrate films formed at liquid/liquid interfaces. I. Morphology of hydrate films. Chemical Engineering Science, 56(14), 4331–4338. https://doi.org/10.1016/s0009-2509(00)00544-3

18. Servio, P., & Englezos, P. (2003). Morphology of methane and carbon dioxide hydrates formed from water droplets. AIChE Journal, 49(1), 269–276. https://doi.org/10.1002/aic.690490125

19. Sundramoorthy, J.D., Hammonds, P., Lal, B., & Phillips, G. (2016). Gas hydrate gas hydrate equilibrium measurement and observation of gas hydrate dissociation with/without a KHI. Procedia Engineering, (148), 870–877. https://doi.org/10.1016/j.proeng.2016.06.476

20. Sai, K., Petlovanyi, M., & Prokopenko, K. (2019). Kinetic features of the dissociation process of gas hydrate deposits. XV International Scientific and Practical Conference «International Trends in Science and Technology». Warsaw, Poland: RS Global S. z O.O., 10–16.

21. Abbasian Rad, S., Rostami Khodaverdiloo, K., Karamoddin, M., Varaminian, F., & Peyvandi, K. (2015). Kinetic study of amino acids inhibition potential of Glycine and l -leucine on the ethane hydrate formation. Journal of Natural Gas Science and Engineering, (26), 819–826. https://doi.org/10.1016/j.jngse.2015.06.053

22. Sa, J.-H., Kwak, G.-H., Han, K., Ahn, D., Cho, S. J., Lee, J. D., & Lee, K.-H. (2016). Inhibition of methane and natural gas hydrate formation by altering the structure of water with amino acids. Scientific Reports, 6(1). https://doi.org/10.1038/srep31582

23. Farhang, F. (2014). Kinetics of the formation of CO2 hydrates in the presence of sodium halides and hydrophobic fumed silica nanoparticles: PhD Thesis. Queensland: The University of Queensland, 177. https://doi.org/10.14264/uql.2014.385

24. Kumar, A., Bhattacharjee, G., Kulkarni, B.D., & Kumar, R. (2015). Role of surfactants in promoting gas hydrate formation. Industrial & Engineering Chemistry Research, 54(49), 12217–12232. https://doi.org/10.1021/acs.iecr.5b03476

25. Hanushevych, K., & Srivastava, V. (2017). Coalbed methane: places of origin, perspectives of extraction, alternative methods of transportation with the use of gas hydrate and nanotechnologies. Mining of Mineral Deposits, 11(3), 23–34. https://doi.org/10.15407/mining11.03.023

 

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